| 1. |
- Calcutt, Hannah, 1988, et al.
(författare)
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The ALMA-PILS survey: first detection of methyl isocyanide (CH3NC) in a solar-type protostar
- 2018
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 617
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Tidskriftsartikel (refereegranskat)abstract
- Methyl isocyanide (CH3NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM), but it is not an abundant molecule, having only been detected towards a handful of objects. Conversely, its isomer, methyl cyanide (CH3CN), is one of the most abundant complex organic molecules detected in the ISM, with detections in a variety of low- and high-mass sources. We use ALMA observations from the Protostellar Interferometric Line Survey (PILS) to search for methyl isocyanide and compare its abundance with that of its isomer methyl cyanide. We use a new line catalogue from the Cologne Database for Molecular Spectroscopy (CDMS) to identify methyl isocyanide lines. We also model the chemistry with an updated version of the three-phase chemical kinetics model MAGICKAL, presenting the first chemical modelling of methyl isocyanide to date. We detect methyl isocyanide for the first time in a solar-type protostar, IRAS 16293-2422 B, and present upper limits for its companion protostar, IRAS 16293-2422 A. Methyl isocyanide is found to be at least 20 times more abundant in source B compared to source A, with a CH3CN/CH3NC abundance ratio of 200 in IRAS 16293-2422 B and >5517 in IRAS 16293-2422 A. We also present the results of a chemical model of methyl isocyanide chemistry in both sources, and discuss the implications on methyl isocyanide formation mechanisms and the relative evolutionary stages of both sources.
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| 2. |
- Coutens, A., et al.
(författare)
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The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium
- 2016
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 590
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Tidskriftsartikel (refereegranskat)abstract
- Formamide (NH2CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. Observations of formamide, related species, and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased, high angular resolution and sensitivity spectral survey of the low-mass protostellar binary IRAS 16293-2422 with the Atacama Large Millimeter/submillimeter Array (ALMA). For the first time, we detect the three singly deuterated forms of NH2CHO (NH2CDO, cis-and trans-NHDCHO), as well as DNCO towards the component B of this binary source. The images reveal that the different isotopologues are all present in the same region. Based on observations of the 13C isotopologues of formamide and a standard 12C/13C ratio, the deuterium fractionation is found to be similar for the three different forms with a value of about 2%. The DNCO/HNCO ratio is also comparable to the D/H ratio of formamide (~1%). These results are in agreement with the hypothesis that NH2CHO and HNCO are chemically related through grain-surface formation.
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| 3. |
- Fayolle, E. C., et al.
(författare)
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Protostellar and cometary detections of organohalogens
- 2017
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Ingår i: Nature Astronomy. - : Springer Science and Business Media LLC. - 2397-3366. ; 1:10, s. 703-708
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Tidskriftsartikel (refereegranskat)abstract
- Organohalogens, a class of molecules that contain at least one halogen atom bonded to carbon, are abundant on the Earth where they are mainly produced through industrial and biological processes(1). Consequently, they have been proposed as biomarkers in the search for life on exoplanets(2). Simple halogen hydrides have been detected in interstellar sources and in comets, but the presence and possible incorporation of more complex halogen-containing molecules such as organohalogens into planet-forming regions is uncertain(3,4). Here we report the interstellar detection of two isotopologues of the organohalogen CH3Cl and put some constraints on CH3F in the gas surrounding the low-mass protostar IRAS 16293-2422, using the Atacama Large Millimeter/submillimeter Array (ALMA). We also find CH3Cl in the coma of comet 67P/Churyumov-Gerasimenko (67P/C-G) by using the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) instrument. The detections reveal an efficient pre-planetary formation pathway of organohalogens. Cometary impacts may deliver these species to young planets and should thus be included as a potential abiotical production source when interpreting future organohalogen detections in atmospheres of rocky planets.
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| 4. |
- Jorgensen, J. K., et al.
(författare)
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The ALMA Protostellar Interferometric Line Survey (PILS) First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA
- 2016
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 595, s. Art no A117-
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Tidskriftsartikel (refereegranskat)abstract
- Context. The inner regions of the envelopes surrounding young protostars are characterized by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. The Atacama Large Millimeter/submillimeter Array (ALMA) provides an unprecedented view of these regions zooming in on solar system scales of nearby protostars and mapping the emission from rare species. Aims. The goal is to introduce a systematic survey, the Protostellar Interferometric Line Survey (PILS), of the chemical complexity of one of the nearby astrochemical templates, the Class 0 protostellar binary IRAS 16293 2422, using ALMA in order to understand the origin of the complex molecules formed in its vicinity. In addition to presenting the overall survey, the analysis in this paper focuses on new results for the prebiotic molecule glycolaldehyde, its isomers, and rarer isotopologues and other related molecules. Methods. An unbiased spectral survey of IRAS 16293 2422 covering the full frequency range from 329 to 363 GHz (0.8 mm) has been obtained with ALMA, in addition to a few targeted observations at 3.0 and 1.3 mm. The data consist of full maps of the protostellar binary system with an angular resolution of 0.5 '' (60 AU diameter), a spectral resolution of 0.2 km s(-1), and a sensitivity of 4-5 mJy beam(-1) km s(-1), which is approximately two orders of magnitude better than any previous studies. Results. More than 10 000 features are detected toward one component in the protostellar binary, corresponding to an average line density of approximately one line per 3 km s(-1). Glycolaldehyde; its isomers, methyl formate and acetic acid; and its reduced alcohol, ethylene glycol, are clearly detected and their emission well-modeled with an excitation temperature of 300 K. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the interstellar medium (ISM). The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center these two species are over-abundant relative to methanol, possibly an indication of formation of the species at low temperatures in CO-rich ices during the infall of the material toward the central protostar. Both C-13 and the deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximate to 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde, in contrast to previous estimates for methanol and recent suggestions of significant equilibration between water and-OH functional groups at high temperatures. Measurements of the C-13-species lead to a C-12:C-13 ratio of approximate to 30, lower than the typical ISM value. This low ratio may reflect an enhancement of (CO)-C-13 in the ice due to either ion-molecule reactions in the gas before freeze-out or to differences in the temperatures where (CO)-C-12 and (CO)-C-13 ices sublimate. Conclusions. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle. Systematic surveys of the molecules thought to be chemically related, as well as the accurate measurements of their isotopic composition, hold strong promise for understanding the origin of prebiotic molecules in the earliest stages of young stars.
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| 5. |
- Calcutt, Hannah, 1988, et al.
(författare)
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The ALMA-PILS survey: propyne (CH3CCH) in IRAS 16293–2422
- 2019
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 631
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Tidskriftsartikel (refereegranskat)abstract
- Context. Propyne (CH3CCH), also known as methyl acetylene, has been detected in a variety of environments, from Galactic star-forming regions to extragalactic sources. These molecules are excellent tracers of the physical conditions in star-forming regions, allowing the temperature and density conditions surrounding a forming star to be determined. Aims. This study explores the emission of CH3CCH in the low-mass protostellar binary, IRAS 16293–2422, and examines the spatial scales traced by this molecule, as well as its formation and destruction pathways. Methods. Atacama Large Millimeter/submillimeter Array (ALMA) observations from the Protostellar Interferometric Line Survey (PILS) were used to determine the abundances and excitation temperatures of CH3CCH towards both protostars. This data allows us to explore spatial scales from 70 to 2400 au. This data is also compared with the three-phase chemical kinetics model MAGICKAL, to explore the chemical reactions of this molecule. Results. CH3CCH is detected towards both IRAS 16293A and IRAS 16293B, and is found the hot corino components, one around each source, in the PILS dataset. Eighteen transitions above 3σ are detected, enabling robust excitation temperatures and column densities to be determined in each source. In IRAS 16293A, an excitation temperature of 90 K and a column density of 7.8 × 1015 cm−2 best fits the spectra. In IRAS 16293B, an excitation temperature of 100 K and 6.8 × 1015 cm−2 best fits the spectra. The chemical modelling finds that in order to reproduce the observed abundances, both gas-phase and grain-surface reactions are needed. The gas-phase reactions are particularly sensitive to the temperature at which CH4 desorbs from the grains. Conclusions. CH3CCH is a molecule whose brightness and abundance in many different regions can be utilised to provide a benchmark of molecular variation with the physical properties of star-forming regions. It is essential when making such comparisons, that the abundances are determined with a good understanding of the spatial scale of the emitting region, to ensure that accurate abundances are derived.
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| 6. |
- Jacobsen, S. K., et al.
(författare)
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The ALMA-PILS survey: 3D modeling of the envelope, disks and dust filament of IRAS 16293–2422
- 2018
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 612
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Tidskriftsartikel (refereegranskat)abstract
- Context. The Class 0 protostellar binary IRAS 16293–2422 is an interesting target for (sub)millimeter observations due to, both, the rich chemistry toward the two main components of the binary and its complex morphology. Its proximity to Earth allows the study of its physical and chemical structure on solar system scales using high angular resolution observations. Such data reveal a complex morphology that cannot be accounted for in traditional, spherical 1D models of the envelope. Aims. The purpose of this paper is to study the environment of the two components of the binary through 3D radiative transfer modeling and to compare with data from the Atacama Large Millimeter/submillimeter Array. Such comparisons can be used to constrain the protoplanetary disk structures, the luminosities of the two components of the binary and the chemistry of simple species. Methods. We present 13CO, C17O and C18O J=3–2 observations from the ALMA Protostellar Interferometric Line Survey (PILS), together with a qualitative study of the dust and gas density distribution of IRAS 16293-2422. A 3D dust and gas model including disks and a dust filament between the two protostars is constructed which qualitatively reproduces the dust continuum and gas line emission. Results. Radiative transfer modeling in our sampled parameter space suggests that, while the disk around source A could not be constrained, the disk around source B has to be vertically extended. This puffed-up structure can be obtained with both a protoplanetary disk model with an unexpectedly high scale-height and with the density solution from an infalling, rotating collapse. Combined constraints on our 3D model, from observed dust continuum and CO isotopologue emission between the sources, corroborate that source A should be at least six times more luminous than source B. We also demonstrate that the volume of high-temperature regions where complex organic molecules arise is sensitive to whether or not the total luminosity is in a single radiation source or distributed into two sources, affecting the interpretation of earlier chemical modeling efforts of the IRAS 16293-2422 hot corino which used a single-source approximation. Conclusions. Radiative transfer modeling of source A and B, with the density solution of an infalling, rotating collapse or a protoplan- etary disk model, can match the constraints for the disk-like emission around source A and B from the observed dust continuum and CO isotopologue gas emission. If a protoplanetary disk model is used around source B, it has to have an unusually high scale-height in order to reach the dust continuum peak emission value, while fulfilling the other observational constraints. Our 3D model requires source
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| 7. |
- Ligterink, N. F. W., et al.
(författare)
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The ALMA-PILS survey: Stringent limits on small amines and nitrogen-oxides towards IRAS 16293–2422B
- 2018
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 619
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Tidskriftsartikel (refereegranskat)abstract
- Context. Hydroxylamine (NH2OH) and methylamine (CH3NH2) have both been suggested as precursors to the formation of amino acids and are therefore, of interest to prebiotic chemistry. Their presence in interstellar space and formation mechanisms, however, are not well established. Aims. We aim to detect both amines and their potential precursor molecules NO, N2O, and CH2NH towards the low-mass protostellar binary IRAS 16293–2422, in order to investigate their presence and constrain their interstellar formation mechanisms around a young Sun-like protostar. Methods. ALMA observations from the unbiased, high-angular resolution and sensitivity Protostellar Interferometric Line Survey (PILS) are used. Spectral transitions of the molecules under investigation are searched for with the CASSIS line analysis software. Results. CH2NH and N2O are detected for the first time, towards a low-mass source, the latter molecule through confirmation with the single-dish TIMASSS survey. NO is also detected. CH3NH2 and NH2OH are not detected and stringent upper limit column densities are determined. Conclusions. The non-detection of CH3NH2 and NH2OH limits the importance of formation routes to amino acids involving these species. The detection of CH2NH makes amino acid formation routes starting from this molecule plausible. The low abundances of CH2NH and CH3NH2 compared to Sgr B2 indicate that different physical conditions influence their formation in low- and high-mass sources.
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| 8. |
- van der Wiel, M. H. D., et al.
(författare)
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The ALMA-PILS survey: gas dynamics in IRAS 16293-2422 and the connection between its two protostars
- 2019
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 626
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Tidskriftsartikel (refereegranskat)abstract
- Context. The majority of stars form in binary or higher order systems. The evolution of each protostar in a multiple system may start at different times and may progress differently. The Class 0 protostellar system IRAS 16293-2422 contains two protostars, "A" and "B", separated by similar to 600 au and embedded in a single, 10(4) au scale envelope. Their relative evolutionary stages have been debated. Aims. We aim to study the relation and interplay between the two protostars A and B at spatial scales of 60 au up to similar to 10(3) au. Methods. We selected molecular gas line transitions of the species CO, H2CO, HCN, CS, SiO, and C2H from the ALMA-PILS spectral imaging survey (329-363 GHz) and used them as tracers of kinematics, density, and temperature in the IRAS 16293-2422 system. The angular resolution of the PILS data set allows us to study these quantities at a resolution of 0.5 '' (60 au at the distance of the source). Results. Line-of-sight velocity maps of both optically thick and optically thin molecular lines reveal: (i) new manifestations of previously known outflows emanating from protostar A; (ii) a kinematically quiescent bridge of dust and gas spanning between the two protostars, with an inferred density between 4 x 10(4) cm(-3) and similar to 3 x 10(7) cm(-3); and (iii) a separate, straight filament seemingly connected to protostar B seen only in C2H, with a flat kinematic signature. Signs of various outflows, all emanating from source A, are evidence of high-density and warmer gas; none of them coincide spatially and kinematically with the bridge. Conclusions. We hypothesize that the bridge arc is a remnant of filamentary substructure in the protostellar envelope material from which protostellar sources A and B have formed. One particular morphological structure appears to be due to outflowing gas impacting the quiescent bridge material. The continuing lack of clear outflow signatures unambiguously associated to protostar B and the vertically extended shape derived for its disk-like structure lead us to conclude that source B may be in an earlier evolutionary stage than source A.
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